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Optical/fluorescence quenching for O2 measurement

The oxygen measurement technique is based upon the fluorescence quenching of a metal organic fluorescent dye immobilized in a gas permeable hydrophobic polymer. The dye absorbs light in the blue region and fluoresces within the red region of the spectrum. The presence of oxygen quenches the fluorescent light from the dye as well as its lifetime. The quenching process is a purely collisional dynamic where the energy from the excited fluorescent dye is transferred to the oxygen molecule during a collision, hence, reducing the emission intensity as well as the fluorescent lifetime of the dye. Thus, the oxygen content of the enclosed space is not changed by the measurement process.

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